PO 36: Define the following terms

  1. Soil pH
  2. Exchangeable acidity
  3. Buffer pH
  4. Alkalinity

Soil pH is the negative log of the H+ ion concentration: pH = -log H+ = log 1/H+.  The more H+ there is, the lower the pH and the greater the acidity.

  • pH 7.0 = -log 0.0000001 = log 1/10-7
  • pH 6.0 = -log 0.000001 = log 1/10-6
  • Properties of pH
    • The pH scale goes from 0 – 14.  pH < 7 is acidic, while pH = 7 is neutral (neither acid nor base), and pH > 7 is basic (alkaline).
    • 1 pH unit represents a tenfold change in acidity.  Thus, pH 5 is ten times more acidic than pH 6, and 100 times more acidic than pH 7.
  • Soils range between pH 3.5 and 9.  Hydrogen (H+) and aluminum ions (Al3+) and complexes are two primary sources of soil acidity.  Northeastern mineral soils generally have pH values between 4.5 – 8.2, while Northeastern muck soils tend to fall between 3.5 – 8.2.

Exchangeable acidity is a measure of the soil's ability to withstand a change in pH upon lime addition.  The higher the exchangeable acidity of a soil, the more lime is needed for a particular pH change.